Consumer Energy Report is now Energy Trends Insider -- Read More »

By Robert Rapier on Dec 14, 2008 with no responses

Carbon Sequestration in Practice


First of its Kind: Sequestered Carbon in Sneek, the Netherlands

Back in March, I left my job with ConocoPhillips to become the Engineering Director for London-based Accsys Technologies, PLC (but my work is focused within the wholly-owned Titan Wood subsidiaries). I explained the circumstances behind my decision to switch employers here. I stated at that time that I would continue to focus my writing on energy and the environment, and not use my platform to start promoting my new company – even though it is focused on environmental technologies. I think it’s fair to say that I have kept to my word. However, I did say that at some point I would write a more extensive article on exactly what it is that my new company is doing. This is that article, with ties into energy, the environment, sustainability, and carbon capture.

A Brief Chemical Tutorial

In a nutshell, Titan Wood chemically modifies fast growing softwood species like (but not limited to) Radiata pine in a way that results in their performance characteristics being superior to some of the best tropical hardwoods such as teak. It is important to note that the modification we make is at the molecular level; we do not impregnate the wood with chemical preservatives that can leach out into the environment. Wood treatment processes like Chromated Copper Arsenate (CCA) fall into this latter category. Further, disposal of treated wood can be a nightmare, as many treatment processes result in the wood being classified as hazardous waste.

Following is a brief explanation of the science behind our process, in mostly layman’s terms. Wood is a very complex material, composed of many complex organic polymers (very long-chain carbon compounds). There are also numerous hydroxyl groups (OH) within wood. Think of a hydroxyl as 2/3rds of a water molecule (HOH, or H2O). Hydroxyl groups are very prone to attracting and releasing water, which is the primary mechanism by which wood shrinks and swells (and this of course makes paint crack and peel). Wood also naturally contains acetyl groups. An acetyl group is essentially an attached acetic acid molecule. Most of you are familiar with acetic acid, because you sometimes put it on your salad in the form of vinegar.


The Chemistry behind Accoya® wood

What we do in our process is remove a large fraction of those hydroxyl groups and replace them with acetyl groups. We call this wood ‘Accoya® wood’, and the properties are remarkably different than the unmodified wood we started out with. Dimensional stability, durability, and UV light resistance are all dramatically improved. Because Accoya absorbs less moisture, thermal insulating properties are also better. Further, Accoya is resistant to attack by termites, microbes, and fungi. Accoya is virtually rot-proof, and yet non-toxic.

Consider the implications. Instead of deforesting tropical rainforests for the highest quality hardwoods, we can essentially make them from trees that grow in northern climates. Wood that is grown via sustainable forestry practices and modified with our acetylation process provides a far more sustainable model for producing high-performance lumber. If the wood is both grown and used locally, so much the better.

How Accoya Sequesters Carbon

That alone is a pretty good story, but there’s more. As we all know, greenhouse gas emissions continue to rise. The recently released World Energy Outlook from the IEA forecast that carbon dioxide emissions from coal combustion would rise from 11.7 billion metric tons in 2006 to 18.6 billion metric tons in 2030. The IEA further predicted that carbon sequestration applications will have limited potential to influence carbon dioxide emissions by 2030.

If we are to slow or halt our carbon dioxide emissions, we need a combination of lower reliance on fossil fuels, coupled with commercially viable carbon sequestration, or carbon capture and storage (CCS) technologies. But the problem with carbon sequestration technologies is that either 1). People can’t figure out how to make money with them, so they aren’t commercialized; or 2). The carbon sequestration is fleeting.

For example, carbon dioxide can certainly be captured from the stacks of coal-fired power plants. A number of technologies will suffice, but they will all add to the cost of electricity. Estimates are that carbon capture would add 25% to the cost of producing electricity from coal. Unless large numbers of consumers are willing to pay this cost – or unless governments mandate it (and therefore mandate that consumers will pay the additional costs), adoption of these sorts of CCS technologies will face strong headwinds.

What about the use of CO2 in enhanced crude oil recovery operations? There are some applications for this, but they are limited. You must still capture and compress the CO2, and then you have to get it to the oil field. Further, that CO2 is being used to produce more oil, which will subsequently produce more CO2. A similar situation applies to the schemes for using algae to capture carbon dioxide from power plants, and then turning that algae into biodiesel. While one could certainly argue that additional energy was produced for each CO2 molecule that was emitted (presuming the energy return is >1.0), at the end of the cycle the CO2 originating from the coal still ends up in the atmosphere.

However, I believe Titan Wood has a truly commercial carbon sequestration application. To my knowledge it is the best (only?) commercial solution in existence. Here is why I believe that.

You know that when a tree grows, it extracts carbon dioxide from the air, converts it via photosynthesis into various biopolymers, and stores the carbon as wood, leaves, etc. Left alone, a tree will uptake carbon dioxide as it grows, but it will eventually die and decompose, returning the carbon dioxide back to the atmosphere. If you could instead take the tree and just bury it deep within the earth, the carbon would be sequestered. This is in fact similar to how all of the carbon in oil, coal, and gas got sequestered in the first place. Ancient plants and animals died and were buried, and the heat and pressure of the earth turned them into fossil fuels.

Of course one can’t make money by growing trees and burying them. So, what else can you do? You could build with wood, and that also sequesters carbon during the lifetime of the application. Because Accoya is modified to resist rot, the carbon can be sequestered for much longer. That’s appealing, but it isn’t the most compelling argument. In fact, you could make that same argument about wood that is treated with toxic treatments – it can sequester carbon for a long period of time (with the obvious negative of the chemicals leeching into the environment).

No, the really compelling aspect about Accoya is that the improved characteristics make it a viable replacement for metals, plastics, and even concrete in certain applications. You can take a very fast growing tree like pine, and modify it so that it can not only replace tropical hardwoods, but it can in some instances replace the steel in a bridge. That’s where the carbon sequestration potential comes into play.

Imagine that instead of making window frames out of plastic (which comes from a fossil fuel) or aluminum (which requires a lot of electricity to produce), you made them out of Accoya. Not only have you avoided carbon emissions, but you have sequestered carbon in a long-lasting application.

Imagine that instead of constructing a bridge out of steel and concrete (both very fossil-fuel intensive), you made it out of Accoya. Again, you have avoided carbon emissions, and you have sequestered carbon. Note that neither of these scenarios is hypothetical. Accoya is currently being used in window frames, and a pair of heavy-traffic bridges is under construction right now in Sneek, the Netherlands. Kudos to the Dutch government for their foresight. The first bridge has been completed and is shown in the opening picture. (See this article for more information). Bear in mind that this bridge is certified to support 60 tons, making it the only wooden bridge in the world certified to support such a heavy load. That makes it the first of its kind.

(As an aside, in 1988 the U.S. Congress passed the Timber Bridge Initiative, to promote the use of timber in bridges. This initiative currently resides at the Forest Products Lab of the U.S. Forestry Service, but we have not yet been in contact with them regarding the possibility of building Accoya bridges in the U.S.)

What is the potential for carbon sequestration? I have done some calculations on that, shown below.

Carbon Sequestration Potential of Accoya

Per this reference:

According to analysis by JATO Dynamics, CO2 emissions in the top five markets dropped by 0.3 g/km in through the first seven months of 2007 compared to the same time last year. A volume-weighted average of new cars sold in the period yielded an average of 160.5 g/km for the fleet.

That means that the average European car emits (160.5/44 g CO2/mol) = 3.65 moles CO2 per km traveled.

The density of Radiata pine is roughly 500 kg/m3. According to University of Wisconsin Professor Emeritus Roger Rowell (and from other sources I have checked), carbon represents about 50% of that, or 250 kg/m3. In chemistry speak, that is (250,000 g/12 g mol) = 20,833 moles of carbon per m3 of wood, which is equal to the number of moles of carbon dioxide that were removed from the atmosphere.

Our Arnhem plant has a nameplate capacity of 30,000 m3/year of finished wood (and the next plant will be much larger). Then the carbon sequestration potential from the Arnhem plant is 20,833* 30,000 = 625 million moles of carbon per year.

Put in terms of the average European car, that means that the output of our relatively small Arnhem plant could sequester the carbon emissions of 625 million moles/(3.65 moles per km) = 171 million km of driving. The average European drives around 11,000 km/yr according to this chart. This translates to sequestration of the carbon emissions of 171 million/11,000 = 15,545 cars per year.

I am not aware of any other technology that can make this claim.

Conclusion

I believe we have a good story in Accoya. I barely scratched the surface of the advantages, which extend to painted surfaces lasting much longer (more avoided emissions, and less fossil fuels for paint manufacture). Our plans at present are to continue to manufacture Accoya in the Netherlands, and to license the technology. The second Accoya plant is being built by our licensee, Diamond Wood, in China. The third plant will be built by our licensee Al Rajhi in the Middle East. Serious discussions are taking places with other prospective licensees around the world, including several in North America.

The nameplate capacity of our first plant in Arnhem, the Netherlands, is 30,000 m3 of wood/year. This output can potentially sequester the carbon emissions of over 15,000 cars per year in Europe. The total offset is equivalent to an annual distance driven of 171 million km. Note that this presumes that we have used Accoya in an application that normally uses metal/plastics/concrete, etc. It does not take into consideration the fact that our life-cycle-assessment (LCA) shows that the energy inputs into producing concrete, steel, etc. are also higher than for producing Accoya – nor that we are avoiding the harvesting of tropical hardwoods. In other words, I believe this should be a conservative estimate.

While I have given you the technical spiel, I am not the guy to answer questions about licensing, sales, etc. If you want some information along those lines, please contact Starla Middlebrooks (Starla ‘dot’ Middlebrooks ‘at’ titanwood ‘dot’ com) at our Dallas offices.

Questions and (My) Answers to Various Inquiries

People have asked me lots of interesting questions around the company and the product. One sort of funny story related to this is that at this year’s ASPO conference in Sacramento, I escaped the talks a bit early to have a quick bite, as I was on an evening panel session. A few minutes later, Bob Hirsch walked in and asked if he could join me. I was delighted, and thought I would get to quiz him about The Hirsch Report. Instead, he spent the next half hour asking me all sorts of questions about Accoya. We were joined by Kjell Aleklett, and he also wanted to talk about wood. After we finished talking, I reflected on how funny it was to have the three of us sitting there, all passionate about oil depletion and energy in general, and all we talked about was wood.

Anyway, here are a few of the sorts of questions that seem to come up most frequently.

Q. Doesn’t the process itself use a lot of energy? A lot more than say, planting a tree and waiting a few years.

A. No. When you grow a tree, like a fast-growing softwood, what happens? It either grows to maturity, eventually dies, and releases its carbon dioxide back to the atmosphere. Or, it is cut down and used in an application that results in it releasing its carbon back to the atmosphere in much less than 100 years.

What happens with Accoya is that you can make a harvest every 20 years and put it into a long-term application. When you put it into an application that is typically aluminum or steel, you have a dual-win: It takes less energy to make Accoya, and you have sequestered carbon where you would have placed steel.

Of course you also have a big benefit by using it for applications typically reserved for tropical timber in that you displace tropical timber with softwoods.

Q. Can Accoya eventually be cost-competitive with other treated woods?

A. That depends on what you mean by cost-competitive. Is it as cheap as arsenic-treated wood? No, but arsenic-treated wood is toxic and disposal is problematic. Likewise, there are similar issues with other cheap wood treatments like pentachlorophenol, creosote, borate, etc. Accoya is no more toxic than regular wood. There is no toxic residue from the treatment.

Q. Seems ironic. Other treated wood is less likely to be burned at the end of its structural life, so the toxic wood is actually more likely to sequester carbon for more than 100 years than is the Accoya, even if the toxic wood is otherwise worse for the environment.

A. No, as that misses two key points. You touched on one in your last sentence. The reason toxic wood eventually fails is because it has leached its components out into the environment. So it continues to decompose at the landfill, albeit at a slower rate than normal wood.

But the key point is this: The acetylation treatment not only makes the wood resistance to biological attack (as do toxic treatments), but it also imparts other beneficial characteristics to the wood, which is the real bonus.

Toxic treated wood doesn’t become more dimensionally stable. A toxic-treated pine is still a softwood. An acetylated pine becomes comparable to a tropical hardwood. The durability and dimensional stability of Accoya exceeds that of teak. See here and here. Now you can go build bridges out of it, something you can’t do with the toxic treated woods. Thus, the acetylation opens up new applications, so there is much greater carbon sequestration potential.

Q. OK, I give. What’s the catch?

A. The ‘catch’ is pretty straightforward. Accoya is obviously more expensive than untreated softwood. And unless customers understand the whole story, they may opt for a cheaper, but inferior option. My job as Engineering Director is to make sure we are running our process in the most efficient manner, and therefore keeping our costs at a minimum.

The other catch is that the market for building materials is presently pretty poor, as a result of the overall economic crisis. So we are swimming upstream against that current.

Q. So are you saying that this is the solution to rising carbon dioxide emissions?

A. It can be a tool in the arsenal. It may be the only tool in the arsenal at present. (If you believe there to be other practical carbon sequestration applications, please let me know and I will amend this). To make a bigger dent in carbon emissions, we would need to start replacing more metals and plastics with Accoya (wooden refrigerators, anyone?).

You can find answers to lots of other questions in our FAQ. Now back to your regularly scheduled programming (even though I think the subject matter here is topical).

Note: As always, if you spot any errors, please call them to my attention.